Publications in 2025
塩化亜鉛触媒を用いる芳香族ニトリルへのグリニャール付加反応の理論的研究
吉川 武司*, 梅澤 美帆, 椿 紗穂里, 坂田 健, 波多野 学
J. Comput. Chem., Jpn. 2025, 24(1), 10-13.
DOI: 10.2477/jccj.2024-0037
Publication Date: March 29, 2025
The Latest Insights into Multiply Selective Diels–Alder Reactions Using a Chiral-Cavity-Structured Lewis-Acidic Boron Catalyst
Kai Matsui, Kohei Toh, Tatsuhiro Sakamoto, Manabu Hatano*, Kazuaki Ishihara*
Adv. Synth. Catal. 2025, 367(5), e202401560.
DOI: 10.1002/adsc.202401560
Publication Date: January 21, 2025
Concise Synthesis of Polyacyloxy Cyclic Ethers Using the p-Toluenesulfonic Acid-Catalyzed Cascade Esterification/Cyclization of Polyols
Takeshi Yamada*, Anri Kimura, Saya Takenouchi, Mizuki Sugahara, Mai Yoshioka, Yuhei Monta, Mike Matsuda, Manabu Hatano*
ChemCatChem 2025, 17(4), e202401723.
DOI: 10.1002/cctc.202401723
Publication Date: November 22, 2024
Publications in 2024
Zinc chloride-catalyzed Grignard addition reaction of aromatic nitriles
Manabu Hatano*, Kisara Kuwano, Riho Asukai, Ayako Nagayoshi, Haruka Hoshihara, Tsubasa Hirata, Miho Umezawa, Sahori Tsubaki, Takeshi Yoshikawa*, Ken Sakata*
Chem. Sci. 2024, 15(22), 8569-8577.
DOI: 10.1039/D4SC01659A
Publication Date: May 13, 2024
Effect of the U-Shaped Cavity of Conformationally Flexible Chiral Lewis-Acidic Boron-Based Catalysts in Multiselective Diels–Alder Reactions
Tatsuhiro Sakamoto, Kohei Toh, Kai Matsui, Manabu Hatano*, Kazuaki Ishihara*
Org. Lett. 2024, 26(17), 3607-3611.
DOI: 10.1021/acs.orglett.4c01060
Publication Date: April 18, 2024
2024.11.27 Organic Chemistry Portalに研究成果が紹介された
Topic title: Organocatalyzed C-C Ring Construction: The Zhang Synthesis of Sinulochmodin C
(Monday, December 16, 2024; Douglass F. Taber; University of Delaware)
https://www.organic-chemistry.org/Highlights/2024/16December.shtm
Boron Trifluoride-Mediated Domino Dehydration/Electrophilic Cyclization of Silylalkynols Leading to 2,3-Fused Tricyclic Benzofulvenes
Takashi Okitsu*, Takeshi Yoshikawa*, Mai Morohashi, Kokoro Aoki, Takayuki Yakura, Ken Sakata, Manabu Hatano
Org. Lett. 2024, 26(8), 1652-1656.
DOI: 10.1021/acs.orglett.4c00123
Publication Date: February 22, 2024
Publications in 2023
Dearomative Intramolecular Diels–Alder/Sulfur Extrusion Reaction of Thiophenes with Alkynes Using peri-Substituted Naphthalene as a Tether
Takashi Okitsu*, Yoshiki Shinohara, Haoran Luo, Manabu Hatano, Takayuki Yakura*
Chem. Asian J. 2024, 19(4), e202301031.
DOI: 10.1002/asia.202301031
Publication Date: December 11, 2023
Chiral Macrocyclic Catalysts for the Enantioselective Addition of Lithium Acetylides to Ketones
Kenji Yamashita, Yuji Tabata, Katsuya Yamakawa, Takuya Mochizuki, Kai Matsui, Manabu Hatano*, Kazuaki Ishihara*
J. Am. Chem. Soc. 2023, 145(48), 26238-26248.
DOI: 10.1021/jacs.3c08905
Publication Date: November 4, 2023
X (旧ツイッター) https://x.com/J_A_C_S/status/1720995779832160670?s=20
当該号のカバーアートを飾りました
December 6, 2023 Vol. 145 Issue 48
https://pubs.acs.org/toc/jacsat/145/48
Photocatalytic Regioselective Hydrofunctionalization of 1,4-Diaryl-1,3-butadienes Using O-, N-, and C-Nucleophiles
Tsubasa Hirata,* Ayumi Ikegami, Manabu Hatano*
Asian J. Org. Chem. 2023, 12(12), e202300486.
DOI: 10.1002/ajoc.202300486
Publication Date: October 24, 2023
2,2′-Biphenol-Derived Phosphoric Acid Catalyst for the Dehydrative Esterification of Carboxylic Acids with Alcohols
Manabu Hatano*, Chiaki Nishioka, Ayaka Mimura, Risa Kimura, Yuki Okuda, Takeshi Yamada, Ken Sakata*
Synlett 2023, 34(20), 2508-2514. [cluster: Special Issue Dedicated to Prof. Hisashi Yamamoto]
DOI: 10.1055/s-0042-1752738
Publication Date: July 10, 2023
2024.8.27 Organic Chemistry Portalに研究成果が紹介された
Topic title: 2,2'-Biphenol-Derived Phosphoric Acid Catalyst for the Dehydrative Esterification of Carboxylic Acids with Alcohols
Publications in 2022
Multiselective Diels–Alder Reaction of α-Arylacroleins Catalyzed by Boron Tribromide-Assisted Chiral Phosphoric Acids
Kai Matsui, Kohei Toh, Manabu Hatano*, Kazuaki Ishihara*
Org. Lett. 2022, 24(35). 6483-6488.
DOI: 10.1021/acs.orglett.2c02747
Publication Date: August 26, 2022
2023.7.31 Organic Chemistry Portalに研究成果が紹介された
Topic title: Organocatalyzed C-C Ring Construction: The Takao Synthesis of Puraquinonic Acid (31 July 2023 - Douglass F. Taber) https://www.organic-chemistry.org/Highlights/2023/31July.shtm
Rapid Synthesis of Polycyclic Aromatic Compounds by Iodocyclization of Ynamides
Takashi Okitsu*, Maho Itoh, Ayaka Inui, Emiko Muta, Ryota Nakamoto, Yuta Adachi, Akimori Wada, Manabu Hatano
Asian J. Org. Chem. 2022, 11(8), e202200275
DOI: 10.1002/ajoc.202200275
Publication Date: June 8, 2022
Publications in 2021
Cp*RhIII/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes
Jumpei Hirose, Takumi Wakikawa, Shun Satake, Masahiro Kojima, Manabu Hatano, Kazuaki Ishihara, Tatsuhiko Yoshino*, Shigeki Matsunaga*
ACS Catal. 2021, 11(24), 15187–15193.
DOI: 10.1021/acscatal.1c04699
Publication Date: December 7, 2021
有機合成のための新触媒反応101 [執筆を分担]
有機合成化学協会 編、東京化学同人、編集 檜山爲次郎・野崎京子・中尾佳亮・中野幸司、2021.11.2.発刊、ISBN: 9784807920051
[分担] 19. 不斉Diels–Alder反応および関連反応 (pp. 38-39)、80. エステル合成 (pp. 160-161)
波多野 学、石原 一彰
Enantio- and Diastereoselective Carbonyl-Ene Cyclization–Acetalization Tandem Reaction Catalyzed by Tris(pentafluorophenyl)borane-Assisted Chiral Phosphoric Acids
Hideyuki Ishihara, Jianhao Huang, Takuya Mochizuki, Manabu Hatano,* Kazuaki Ishihara*
ACS Catal. 2021, 11(10), 6121–6127.
DOI: 10.1021/acscatal.1c01242
Publication Date: May 6, 2021
2021.11.29 Organic Chemistry Portalに研究成果が紹介された
Topic title: Organocatalyzed C-C Ring Construction (29 November 2021 - Douglass F. Taber)
https://www.organic-chemistry.org/Highlights/2021/29November.shtm
Insight into the Mechanism of the Acylation of Alcohols with Acid Anhydrides Catalyzed by Phosphoric Acid Derivatives
Hiroyuki Hayashi, Shotaro Yasukochi, Tatsuhiro Sakamoto, Manabu Hatano,* Kazuaki Ishihara*
J. Org. Chem. 2021, 86(7), 5197-5212.
DOI: 10.1021/acs.joc.1c00102
Publication Date: March 15, 2021
2022.2.1 Organic Chemistry Portalに研究成果が紹介された
Topic title: Insight into the Mechanism of the Acylation of Alcohols with Acid Anhydrides Catalyzed by Phosphoric Acid Derivatives
Chemoselective Transesterification of Methyl (Meth)acrylates Catalyzed by Sodium(I) or Magnesium(II) Aryloxides
Jie Qi Ng, Hiro Arima, Takuya Mochizuki, Kohei Toh, Kai Matsui, Manussada Ratanasak, Jun-Ya Hasegawa,* Manabu Hatano,* Kazuaki Ishihara*
ACS Catal. 2021, 11(1), 199-207.
DOI: 10.1021/acscatal.0c04217
Publication Date: December 16, 2020
Reusable Silica-Supported Ammonium BINSate Catalysts for Enantio- and Diastereoselective Friedel-Crafts-Type Double Aminoalkylation of N-Alkylpyrroles with Aldimines
Manabu Hatano,* Xue Zhao, Takuya Mochizuki, Kyogo Maeda, Ken Motokura,* Kazuaki Ishihara*
Asian J. Org. Chem. 2021, 10(2), 360-365.
DOI: 10.1002/ajoc.202000603
Publication Date: December 13, 2020
Publications in 2020
Enantioselective Aza-Friedel-Crafts Reaction of Indoles and Pyrroles Catalyzed by Chiral C1-Symmetric Bis(phosphoric Acid)
Manabu Hatano, Kohei Toh, Kazuaki Ishihara*
Org. Lett. 2020, 22(24), 9614-9620.
DOI: 10.1021/acs.orglett.0c03662
Publication Date: December 9, 2020
■Synfactsにハイライトされました
Brønsted-Acid-Catalyzed Enantioselective Aza-Friedel-Crafts Reaction
SYNFACTS Contributors: Hisashi Yamamoto, Wataru Muramatsu
Synfacts 2021, 17(03), 0346.
DOI: 10.1055/s-0040-1706139
Publication Date: Feburary 16, 2021
神戸薬科大学 神戸薬科大 神戸薬大 波多野 波多野学 山田健 平田翼 生命有機化学研究室 薬学部 有機化学 有機合成 有機合成化学 有機触 媒 グリーンケミストリー 不斉触媒 波多野研 波多野学研 波多野研究室 波多野学研究室 兵庫 兵庫県 神戸 神戸市
Manabu Hatano Takeshi Yamada Tsubasa Hirata
神戸薬科大学・生命有機化学研究室・波多野研究室